I don't recall that I have, no. I do have a few things in the archive on VHS/DVD/Bluray, but I'm too much of a fidget for binge watching. What I obtained was almost pointless – nearly everything gets re-run now we have a multiplicity of channels, but the things I don't have, don't get rerun because it's too old and not sufficiently low-brow for Talking Pictures (et al).
My only hope is that BBC4 digs it out of the archive. EG (I may have some details wrong): James Burke's Connections (circa 1975); or the series of three epic 3-hour documentaries The Restless Earth, The Weather Machine, and The Violent Universe, presented by Magnus Magnusson (IIRC). Having said that, the science may now be so far behind the state of the art that they are irrelevant or incorrect.